Hydrothermal Synthesis,Structure and Character of an Organic-inorganic Compound [Cu(en)(H_2O)(2,2′-bipy)]_2H_3[BW_(12)O_(40)]·2.5H_2O
Suzhi Li
Abstract
Suzhi Li
Abstract
Organic-inorganic compound [Cu(en)(H2O)(2,2′-bipy)]2H3[BW12O40]·2.5H2O has been prepared under hydrothermal conditions and characterized by using elemental analysis,IR and UV spectrometry,XPS,TG,fluorescence spectrometry and X-ray single crystal diffraction analysis.The title compound crystallizes in monoclinic system,P2(1)/c space group,a=1.951 1(2) nm,b=1.229 76(12) nm,c=2.505 9(3) nm,β=91.266(2)°,V=6.011 1(11) nm3,Z=4.In the title compound,the heteropolyanion [BW12O40]5-combines the coordination cation [Cu(en)(H2O)(2,2′-bipy)]+ through electrostatic interaction.
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Organic-inorganic compound [Cu(en)(H2O)(2,2′-bipy)]2H3[BW12O40]·2.5H2O has been prepared under hydrothermal conditions and characterized by using elemental analysis,IR and UV spectrometry,XPS,TG,fluorescence spectrometry and X-ray single crystal diffraction analysis.The title compound crystallizes in monoclinic system,P2(1)/c space group,a=1.951 1(2) nm,b=1.229 76(12) nm,c=2.505 9(3) nm,β=91.266(2)°,V=6.011 1(11) nm3,Z=4.In the title compound,the heteropolyanion [BW12O40]5-combines the coordination cation [Cu(en)(H2O)(2,2′-bipy)]+ through electrostatic interaction.
Key concepts: Monoclinic crystal system, X-ray photoelectron spectroscopy, Hydrothermal circulation, Hydrothermal synthesis, Crystallography, Chemistry, Single crystal, Elemental analysis