2022•Mendeleev CommunicationsRequires access

Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane

N. О. Yarosh, L. V. Zhilitskaya, Irina V. Sterkhova, Mikhail E. Plyaskin, Bagrat А. Shainyan

Abstract

Tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane were synthesized by the reaction of BrMgC CSi(CH 2 Cl)Me 2 with SiCl 4 /GeCl 4 . Their structures were proved by IR, NMR spectroscopy and X-ray analysis, and compared to the results of MP2/6-311G(d,p) calculations.

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Key concepts: Germane, Chemistry, Silane, Medicinal chemistry, Nuclear magnetic resonance spectroscopy, Computational chemistry, Organic chemistry, Silicon