1999Canadian Journal of ChemistryRequires access

A new silicon-mediated nitrogen to oxygen rearrangement

Stefano Talami, Charles JM Stirling

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Abstract

Migration of silicon from nitrogen to oxygen has been quantified with respect to the distance between migration termini, substituents at silicon, and substitution on the chain linking oxygen to nitrogen.Key words: silicon migration, nitrogen to oxygen, penta coordinate intermediate.

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What this paper is about

Migration of silicon from nitrogen to oxygen has been quantified with respect to the distance between migration termini, substituents at silicon, and substitution on the chain linking oxygen to nitrogen.Key words: silicon migration, nitrogen to oxygen, penta coordinate intermediate.

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OpenAlex reports 5 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Migration of silicon from nitrogen to oxygen has been quantified with respect to the distance between migration termini, substituents at silicon, and substitution on the chain linking oxygen to nitrogen.Key words: silicon migration, nitrogen to oxygen, penta coordinate intermediate.

Key concepts: Chemistry, Silicon, Oxygen, Nitrogen, Oxygen atom, Photochemistry, Inorganic chemistry, Organic chemistry

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