A new silicon-mediated nitrogen to oxygen rearrangement
Stefano Talami, Charles JM Stirling
Abstract
Stefano Talami, Charles JM Stirling
Abstract
Migration of silicon from nitrogen to oxygen has been quantified with respect to the distance between migration termini, substituents at silicon, and substitution on the chain linking oxygen to nitrogen.Key words: silicon migration, nitrogen to oxygen, penta coordinate intermediate.
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Migration of silicon from nitrogen to oxygen has been quantified with respect to the distance between migration termini, substituents at silicon, and substitution on the chain linking oxygen to nitrogen.Key words: silicon migration, nitrogen to oxygen, penta coordinate intermediate.
Key concepts: Chemistry, Silicon, Oxygen, Nitrogen, Oxygen atom, Photochemistry, Inorganic chemistry, Organic chemistry