Mechanistic insights into acid-affected hydrogenolysis of glycerol to 1,3-propanediol over an Ir–Re/SiO 2 catalyst
Zheng Zhou, Xin Ren, Yueqiang Cao, Yi‐An Zhu, Jinghong Zhou, Xinggui Zhou
Abstract
Zheng Zhou, Xin Ren, Yueqiang Cao, Yi‐An Zhu, Jinghong Zhou, Xinggui Zhou
Abstract
O* over an IrRe catalyst. The positive effects of solid acids are elucidated to originate from the reduced energy barrier of the RDS by H protons, while the negative ones of liquid acids are from excessively strong adsorption of anions.
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O* over an IrRe catalyst. The positive effects of solid acids are elucidated to originate from the reduced energy barrier of the RDS by H protons, while the negative ones of liquid acids are from excessively strong adsorption of anions.
Key concepts: Hydrogenolysis, Propanediol, Catalysis, Glycerol, Chemistry, Adsorption, Dehydration, 1,3-Propanediol