2022•Chemical CommunicationsRequires access

Mechanistic insights into acid-affected hydrogenolysis of glycerol to 1,3-propanediol over an Ir–Re/SiO 2 catalyst

Zheng Zhou, Xin Ren, Yueqiang Cao, Yi‐An Zhu, Jinghong Zhou, Xinggui Zhou

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Abstract

O* over an IrRe catalyst. The positive effects of solid acids are elucidated to originate from the reduced energy barrier of the RDS by H protons, while the negative ones of liquid acids are from excessively strong adsorption of anions.

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O* over an IrRe catalyst. The positive effects of solid acids are elucidated to originate from the reduced energy barrier of the RDS by H protons, while the negative ones of liquid acids are from excessively strong adsorption of anions.

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Available abstract

O* over an IrRe catalyst. The positive effects of solid acids are elucidated to originate from the reduced energy barrier of the RDS by H protons, while the negative ones of liquid acids are from excessively strong adsorption of anions.

Key concepts: Hydrogenolysis, Propanediol, Catalysis, Glycerol, Chemistry, Adsorption, Dehydration, 1,3-Propanediol

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