ChemInform Abstract: Boron Trifluoride‐Catalyzed Rearrangement of 2‐Aryloxytetrahydropyrans: A New Entry to C‐Arylglycosidation.
Tadashi Kometani, Hiroyuki Kondo, Yukio Fujimori
Abstract
Tadashi Kometani, Hiroyuki Kondo, Yukio Fujimori
Abstract
Abstract 2‐Aryloxytetrahydropyrans and ‐furans (I) and (IV) rearrange on treatment with boron trifluoride etherate, yielding the 2‐aryl derivatives (II) and (V) as outlined in the reaction scheme.
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Abstract 2‐Aryloxytetrahydropyrans and ‐furans (I) and (IV) rearrange on treatment with boron trifluoride etherate, yielding the 2‐aryl derivatives (II) and (V) as outlined in the reaction scheme.
Key concepts: Boron trifluoride, Chemistry, Catalysis, Boron, Medicinal chemistry, Aryl, Organic chemistry, Alkyl