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1973•Chemistry LettersRequires access

EFFECT OF BORON TRIFLUORIDE ETHERATE ON THE PHOTOREARRANGEMENT OF N-BENZYLANILINES

Junji Furukawa, Kanji Omura

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Abstract

Abstract Irradiation of N-benzylanilines complexed with boron trifluoride (BF3) results in the preferential formation of o-benzylanilines. With optically active N-α-phenethylaniline, increased retention of optical activity in the ortho migrated product was observed as compared to that found in the absence of boron trifluoride etherate (BF3–Et2O).

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What this paper is about

Abstract Irradiation of N-benzylanilines complexed with boron trifluoride (BF3) results in the preferential formation of o-benzylanilines. With optically active N-α-phenethylaniline, increased retention of optical activity in the ortho migrated product was observed as compared to that found in the absence of boron trifluoride etherate (BF3–Et2O).

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Available abstract

Abstract Irradiation of N-benzylanilines complexed with boron trifluoride (BF3) results in the preferential formation of o-benzylanilines. With optically active N-α-phenethylaniline, increased retention of optical activity in the ortho migrated product was observed as compared to that found in the absence of boron trifluoride etherate (BF3–Et2O).

Key concepts: Chemistry, Boron trifluoride, Boron, Medicinal chemistry, Organic chemistry, Catalysis

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EFFECT OF BORON TRIFLUORIDE ETHERATE ON THE PHOTOREARRANGEMENT OF N-BENZYLANILINES — Research Paper | ScholarLens