Study on Simultaneous Electrolysis Depositing of Ni-MnO_2 in Sulphuric Acid System
Luo Yuan
Abstract
Luo Yuan
Abstract
The influence of temperature, current density, pH, cell voltage and manganese ion concentration and nickel ion concentration on Ni MnO 2 simultaneous electrolysis process and the current efficiency was studied Based on the orthogonal experiment results, the best electrolysis technical condition showed as follow: [Ni 2+ ] 90g/L;[Mn 2+ ] 30g/L;pH 3 5;90℃;current density 165A/m 2;=15g/L,cell voltage 2 86V, the cathode efficiency can reach 98 88%, and the anode efficiency nears 100%, the cathode nickel can reach Grade 1 level, and the pureness of the anode manganese dioxide is suit for the cell industry
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The influence of temperature, current density, pH, cell voltage and manganese ion concentration and nickel ion concentration on Ni MnO 2 simultaneous electrolysis process and the current efficiency was studied Based on the orthogonal experiment results, the best electrolysis technical condition showed as follow: [Ni 2+ ] 90g/L;[Mn 2+ ] 30g/L;pH 3 5;90℃;current density 165A/m 2;=15g/L,cell voltage 2 86V, the cathode efficiency can reach 98 88%, and the anode efficiency nears 100%, the cathode nickel can reach Grade 1 level, and the pureness of the anode manganese dioxide is suit for the cell industry
Key concepts: Anode, Electrolysis, Cathode, Manganese, Nickel, Materials science, Current density, Cell voltage