2009Journal of Hechi UniversityRequires access

Synthesis and Crystal Structure of Zn(II) Complex Constructed from 2,3,5,6-Tetramethlytetrephalic Acid

Yang Shi-yao

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Abstract

The complex {[Zn(tmbdc)(DMSO)2]·2(DMSO) }n(tmbdc = 2,3,5,6-tetramethylbenzenedicarboxylate) is synthesized with 2,3,5,6-tetramethlytetrephalic acid and Zn(NO3)2·6H2O by means of diffusion.The crystal structure is confirmed by elemental analysis and X-ray single crystal diffraction.The title complex belongs to monoclinic system with space group C2/c,cell parameters: a=1.219 80(9) nm,b=1.294 63(10) nm,c= 1.784 71(13)nm,V= 2.749 4(4) nm3,Z= 4.The methyl substituents result in the formation of the hydrophobic 1D chain structure of the title complex.

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What this paper is about

The complex {[Zn(tmbdc)(DMSO)2]·2(DMSO) }n(tmbdc = 2,3,5,6-tetramethylbenzenedicarboxylate) is synthesized with 2,3,5,6-tetramethlytetrephalic acid and Zn(NO3)2·6H2O by means of diffusion.The crystal structure is confirmed by elemental analysis and X-ray single crystal diffraction.The title complex belongs to monoclinic system with space group C2/c,cell parameters: a=1.219 80(9) nm,b=1.294 63(10) nm,c= 1.784 71(13)nm,V= 2.749 4(4) nm3,Z= 4.The methyl substituents result in the formation of the hydrophobic 1D chain structure of the title complex.

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Available abstract

The complex {[Zn(tmbdc)(DMSO)2]·2(DMSO) }n(tmbdc = 2,3,5,6-tetramethylbenzenedicarboxylate) is synthesized with 2,3,5,6-tetramethlytetrephalic acid and Zn(NO3)2·6H2O by means of diffusion.The crystal structure is confirmed by elemental analysis and X-ray single crystal diffraction.The title complex belongs to monoclinic system with space group C2/c,cell parameters: a=1.219 80(9) nm,b=1.294 63(10) nm,c= 1.784 71(13)nm,V= 2.749 4(4) nm3,Z= 4.The methyl substituents result in the formation of the hydrophobic 1D chain structure of the title complex.

Key concepts: Monoclinic crystal system, Crystallography, Crystal structure, Chemistry, Zinc, Group (periodic table), Diffraction, Single crystal

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