2002CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION)Requires access

Study on Application of β Zeolite in Cracking Catalyst

Li Li, Cnpc Key

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Abstract

zeolite was synthesized by using hydrothermal method with silica as silicon source, and its physico chemical properties were investigated by using XRD, FT IR, BET etc . USY zeolite and β zeolite were mixed in different proportions as the active components of the catalyst for catalytic cracking. Comprehensive evaluation and comparison were made about the effect of the content of β zeolite in the catalyst on microactivity test (MAT) activity, coke deposition, composition of the gaseous product and RON of the obtained gasoline etc . The effect of P or RE modified β zeolite on the activity of the catalyst, distribution of the products and RON of the obtained gasoline was investigated under the condition of using modified β zeolite taking the part place of USY zeolite. The result showed that, with the increase of the content of β zeolite in the catalyst, the MAT, the i C = 4 content in the gaseous product and the RON of the obtained gasoline increase, while the deposited coke decreases. When the content of β zeolite in the catalyst reaches to a certain value, the i C = 4 content in the gaseous product increases obviously but the MAT decreases. The modification of β zeolite by P or RE was studied, and the catalyst with Pβ zeolite increases the MAT and decreases the deposited coke, but does not obviously affect the composition of gasoline, as compared with the unmodified β zeolite.

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What this paper is about

zeolite was synthesized by using hydrothermal method with silica as silicon source, and its physico chemical properties were investigated by using XRD, FT IR, BET etc . USY zeolite and β zeolite were mixed in different proportions as the active components of the catalyst for catalytic cracking. Comprehensive evaluation and comparison were made about the effect of the content of β zeolite in the catalyst on microactivity test (MAT) activity, coke deposition, composition of the gaseous product and RON of the obtained gasoline etc . The effect of P or RE modified β zeolite on the activity of the catalyst, distribution of the products and RON of the obtained gasoline was investigated under the condition of using modified β zeolite taking the part place of USY zeolite. The result showed that, with the increase of the content of β zeolite in the catalyst, the MAT, the i C = 4 content in the gaseous product and the RON of the obtained gasoline increase, while the deposited coke decreases. When the content of β zeolite in the catalyst reaches to a certain value, the i C = 4 content in the gaseous product increases obviously but the MAT decreases. The modification of β zeolite by P or RE was studied, and the catalyst with Pβ zeolite increases the MAT and decreases the deposited coke, but does not obviously affect the composition of gasoline, as compared with the unmodified β zeolite.

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Available abstract

zeolite was synthesized by using hydrothermal method with silica as silicon source, and its physico chemical properties were investigated by using XRD, FT IR, BET etc . USY zeolite and β zeolite were mixed in different proportions as the active components of the catalyst for catalytic cracking. Comprehensive evaluation and comparison were made about the effect of the content of β zeolite in the catalyst on microactivity test (MAT) activity, coke deposition, composition of the gaseous product and RON of the obtained gasoline etc . The effect of P or RE modified β zeolite on the activity of the catalyst, distribution of the products and RON of the obtained gasoline was investigated under the condition of using modified β zeolite taking the part place of USY zeolite. The result showed that, with the increase of the content of β zeolite in the catalyst, the MAT, the i C = 4 content in the gaseous product and the RON of the obtained gasoline increase, while the deposited coke decreases. When the content of β zeolite in the catalyst reaches to a certain value, the i C = 4 content in the gaseous product increases obviously but the MAT decreases. The modification of β zeolite by P or RE was studied, and the catalyst with Pβ zeolite increases the MAT and decreases the deposited coke, but does not obviously affect the composition of gasoline, as compared with the unmodified β zeolite.

Key concepts: Zeolite, Catalysis, Coke, Gasoline, Fluid catalytic cracking, Product distribution, Cracking, Chemical engineering

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