Effects of HL/HW Composite Zeolite on the Performance of Hydrocarbon Catalytic Cracking Catalyst
Huifang Pan
Abstract
Huifang Pan
Abstract
The mixture of zeolite REUSY and HL/HW composite zeolite with different contents of zeolite HW (IW/IL, the intensity ratio of XRD characteristic peaks for zeolite W and zeolite L, denoted as the content of zeolite HW in HL/HW composite zeolite) was used as the active component of catalytic cracking catalyst. The microactivity test (MAT) was carried out to study the effect of HL/HW composite zeo-lite with different IW/IL values in the cracking catalyst on the activity, product distribution, coke deposition, and research octane number (RON) of obtained gasoline. The results show that when IW/IL value is in the range of 0–0.12, the MAT index and the yield of gasoline in-crease, the specific coke decreases, and the yield of gaseous product first decreases and then increases. When the IW/IL value is higher than 0.12, the MAT index, the yield of gasoline, and yield of gaseous product decrease, and the specific coke increases. When IW/IL value is 0.12, the catalyst shows good performance. Compared with the comparative catalyst (no zeolites L and W introduced), aromatic content of gaso-line product and RON increase by 9.85% and 3.01%, respectively, and olefin content decreases by 1.30%.
A significance statement is not available in the OpenAlex record.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
The mixture of zeolite REUSY and HL/HW composite zeolite with different contents of zeolite HW (IW/IL, the intensity ratio of XRD characteristic peaks for zeolite W and zeolite L, denoted as the content of zeolite HW in HL/HW composite zeolite) was used as the active component of catalytic cracking catalyst. The microactivity test (MAT) was carried out to study the effect of HL/HW composite zeo-lite with different IW/IL values in the cracking catalyst on the activity, product distribution, coke deposition, and research octane number (RON) of obtained gasoline. The results show that when IW/IL value is in the range of 0–0.12, the MAT index and the yield of gasoline in-crease, the specific coke decreases, and the yield of gaseous product first decreases and then increases. When the IW/IL value is higher than 0.12, the MAT index, the yield of gasoline, and yield of gaseous product decrease, and the specific coke increases. When IW/IL value is 0.12, the catalyst shows good performance. Compared with the comparative catalyst (no zeolites L and W introduced), aromatic content of gaso-line product and RON increase by 9.85% and 3.01%, respectively, and olefin content decreases by 1.30%.
Key concepts: Zeolite, Coke, Catalysis, Gasoline, Product distribution, Octane rating, Fluid catalytic cracking, Yield (engineering)