Synthesis,Characterization and Crystal Structure of a Mononuclear Nickel(II) Complex [Ni(nas)_2( phen)_2] with Three-Dimensional Supramolecular Structure

A Nickel( II) complex,[Ni( nas)2( phen)2]( nas = 2-aminonaphthalene-1-sulfonate,phen= 1,10-phenanthroline) was hydrothermally synthesized and structurally characterized by IR,elemental analyses,TGA,solid UV spectrum and single crystal X-ray diffraction. The results show that the structure of the complex belongs to tetragonal crystal system,and crystallized in space group P41212,a =1. 24321( 4) nm,b = 1. 24321( 4) nm,c = 2. 45032( 16) nm,α = 90. 00°,β = 90. 00°,γ = 90. 00°,V =3. 7871( 3) nm3.