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Determination of 10 elements in soil by Inductively Coupled Plasma-Mass Spectrometry with microwave digestion

SU Ron

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Abstract

A method to determine concentrations of 10 elements in soil by Inductively Coupled Plasma-Mass Spectrometry( ICP-MS) with microwave digestion is developed. The effect of disturbance of isotope on soil determination is studied. The detection limits for the method are 0. 01- 0. 46 μg / L. The relative standard deviation( RSD) is less than4. 8%. The recoveries are 92. 3%- 108. 3%. The accuracy and precision of the method are validated by reference materials and the results are consistent with the certified values. This method with good reproducibility and wide linearity is simple and rapid,which is suitable for the analysis of large batches of soil samples.

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What this paper is about

A method to determine concentrations of 10 elements in soil by Inductively Coupled Plasma-Mass Spectrometry( ICP-MS) with microwave digestion is developed. The effect of disturbance of isotope on soil determination is studied. The detection limits for the method are 0. 01- 0. 46 μg / L. The relative standard deviation( RSD) is less than4. 8%. The recoveries are 92. 3%- 108. 3%. The accuracy and precision of the method are validated by reference materials and the results are consistent with the certified values. This method with good reproducibility and wide linearity is simple and rapid,which is suitable for the analysis of large batches of soil samples.

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Available abstract

A method to determine concentrations of 10 elements in soil by Inductively Coupled Plasma-Mass Spectrometry( ICP-MS) with microwave digestion is developed. The effect of disturbance of isotope on soil determination is studied. The detection limits for the method are 0. 01- 0. 46 μg / L. The relative standard deviation( RSD) is less than4. 8%. The recoveries are 92. 3%- 108. 3%. The accuracy and precision of the method are validated by reference materials and the results are consistent with the certified values. This method with good reproducibility and wide linearity is simple and rapid,which is suitable for the analysis of large batches of soil samples.

Key concepts: Inductively coupled plasma mass spectrometry, Microwave digestion, Chemistry, Certified reference materials, Reproducibility, Inductively coupled plasma, Mass spectrometry, Analytical Chemistry (journal)

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