2013Journal of Wuhan Institute of TechnologyRequires access

Performance of dynamic crosslinked polypropylene/ethylene-octene copolymer blends

Xue‐Lian Jiang

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Abstract

Dynamic crosslinked polypropylene/ethylene-octene copolymer(PP/POE)blends were prepared by using dynamic crosslinked method.The torque of PP/POE blends was studied using a Hakke Rheometer.Effect of the amount of DCP and POE on mechanical properties and rheological properties of dynamic crosslinked PP/POE blends was investigated.The results show that the torque of PP/POE blends increases firstly with increasing DCP and then decreases to the balance;the impact strength of the blends increases obviously,but tensile strength decreases slightly with increasing POE content;the suitable proportion of PP/POE is 100∶40,and the optimal amount of DCP is 2% of POE content;the rheological behavior of dynamic crosslinked PP/POE blends belongs to pseudoplastic fluid,the degree of degradation reaction is higher than that of crosslinking reaction at high temperature of 220℃.

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Dynamic crosslinked polypropylene/ethylene-octene copolymer(PP/POE)blends were prepared by using dynamic crosslinked method.The torque of PP/POE blends was studied using a Hakke Rheometer.Effect of the amount of DCP and POE on mechanical properties and rheological properties of dynamic crosslinked PP/POE blends was investigated.The results show that the torque of PP/POE blends increases firstly with increasing DCP and then decreases to the balance;the impact strength of the blends increases obviously,but tensile strength decreases slightly with increasing POE content;the suitable proportion of PP/POE is 100∶40,and the optimal amount of DCP is 2% of POE content;the rheological behavior of dynamic crosslinked PP/POE blends belongs to pseudoplastic fluid,the degree of degradation reaction is higher than that of crosslinking reaction at high temperature of 220℃.

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Available abstract

Dynamic crosslinked polypropylene/ethylene-octene copolymer(PP/POE)blends were prepared by using dynamic crosslinked method.The torque of PP/POE blends was studied using a Hakke Rheometer.Effect of the amount of DCP and POE on mechanical properties and rheological properties of dynamic crosslinked PP/POE blends was investigated.The results show that the torque of PP/POE blends increases firstly with increasing DCP and then decreases to the balance;the impact strength of the blends increases obviously,but tensile strength decreases slightly with increasing POE content;the suitable proportion of PP/POE is 100∶40,and the optimal amount of DCP is 2% of POE content;the rheological behavior of dynamic crosslinked PP/POE blends belongs to pseudoplastic fluid,the degree of degradation reaction is higher than that of crosslinking reaction at high temperature of 220℃.

Key concepts: Materials science, Polypropylene, Rheology, Copolymer, Composite material, Ultimate tensile strength, Octene, Ethylene

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