2009•Chemistry and AdhesionRequires access

Influence of Reactive Emulsifier on Acetic/Acrylic Micro Soap-containing Emulsion Polymerization and Its Performance

Huang Zhi-liang

Abstract

Acetic/acrylic micro soap-containing emulsion with core-shell structure had been prepared with VAc,BA and MMA as monomers.And SVS reactive emulsifier,SDS and OP-10 emulsifier was used.The influence of ratio of soft to hard monomer,kinds and amount of emulsifier,etc.on the properties of emulsions and films were discussed,and the structure and performance of this emulsion were characterized by DSC and TEM.The results show that semi-continuous core-shell polymerization process and proper reactive emulsifier hybrid system will prepare acetic/acrylic in micro soap-containing emulsion with excellent comprehensive performance and its particle size is between 80nm and 100nm.

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Key concepts: Emulsion, Emulsion polymerization, Materials science, Monomer, Polymerization, Chemical engineering, Particle size, Acrylic resin