2003•Journal of Analytical ScienceRequires access

Study on the Colour Reaction of a New Reagent 1-(2,6-dichloro-4-nitrophenyl)-3-(4-nitrophenyl)- Triazene with Cadmium and Its Application

Yang Ming-hua

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Abstract

The coluor reaction of 1-(2,6-dichloro-4-nitrophenyl)-3-(4-nitrophenyl)-triazene (DCNPNPT) with cadium (Ⅱ) was studied. Results show that the yellow complex(1∶3) appears at pH=9.8~11.0 buffer solution of Na 2B 4O 7-NaOH in the presence of Triton X-100. The maximum absorption is at 445 nm, whereas the maxmium negative absorption is at 525 nm. The molar absorptivity is 2.85×10 5 L·mol -1·cm -1 by using dual-wavelength spectrophotometry. This method has been used for the determination of Cd(Ⅱ) in waste water and human hair with satisfactory results.

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What this paper is about

The coluor reaction of 1-(2,6-dichloro-4-nitrophenyl)-3-(4-nitrophenyl)-triazene (DCNPNPT) with cadium (Ⅱ) was studied. Results show that the yellow complex(1∶3) appears at pH=9.8~11.0 buffer solution of Na 2B 4O 7-NaOH in the presence of Triton X-100. The maximum absorption is at 445 nm, whereas the maxmium negative absorption is at 525 nm. The molar absorptivity is 2.85×10 5 L·mol -1·cm -1 by using dual-wavelength spectrophotometry. This method has been used for the determination of Cd(Ⅱ) in waste water and human hair with satisfactory results.

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Available abstract

The coluor reaction of 1-(2,6-dichloro-4-nitrophenyl)-3-(4-nitrophenyl)-triazene (DCNPNPT) with cadium (Ⅱ) was studied. Results show that the yellow complex(1∶3) appears at pH=9.8~11.0 buffer solution of Na 2B 4O 7-NaOH in the presence of Triton X-100. The maximum absorption is at 445 nm, whereas the maxmium negative absorption is at 525 nm. The molar absorptivity is 2.85×10 5 L·mol -1·cm -1 by using dual-wavelength spectrophotometry. This method has been used for the determination of Cd(Ⅱ) in waste water and human hair with satisfactory results.

Key concepts: Chemistry, Molar absorptivity, Triazene, Reagent, Color reaction, Spectrophotometry, Cadmium, Buffer solution

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