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Research Progress in the Asymmetric Reaction Catalyzed by Chiral BINOL Phosphoric Acids

QU Gui-rong

Abstract

This paper reviews the recent research progress(37 references) in the asymmetric reactions catalyzed by chiral phosphoric acids(derived from BINOL as a class of strongly acidic Brnsted acid catalyst). The asymmetric reactions include the transfer hydrogenation reaction,the Friedel-Crafts reaction,the Mannich reaction,the Aza Diels-Alder reaction,the Aza-ene-type reaction,the Pictet-Spengler reaction and so on.

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Available abstract

Key concepts: Chemistry, Phosphoric acid, Catalysis, Mannich reaction, Enantioselective synthesis, Organic chemistry, Friedel–Crafts reaction, Brønsted–Lowry acid–base theory