2011•Guangzhou Chemical IndustryRequires access

Recent Progress of Asymmetric Friedel-Crafts Reactions Catalyzed by Phosphoric Acid Derived from BINOL

Fenghua Geng

Abstract

The chiral phosphoric acid derived from BINOL was an excellent Brnsted acid catalyst in recent years.Now,asymmetric Friedel-Craft(F-C) reaction catalyzed by chiral phosphoric acid became one of the hot topics.The latest progress in the research of chiral phosphoric acid catalysts was reviewed for the asymmetric F-C reaction of imines or enamines.

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Available abstract

Key concepts: Phosphoric acid, Friedel–Crafts reaction, Brønsted–Lowry acid–base theory, Catalysis, Chemistry, Organic chemistry, Organocatalysis, Enantioselective synthesis