2007•Journal of Zhejiang Normal UniversityRequires access

Absorptiophotometric determination of iron in food using 1-(2-thiazolylazo)-2-naphthol-OP system

Keming Fang

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Abstract

In the presence of nonionic surfactant OP,the color reaction of Fe(Ⅱ) with 1-(2-Thiazolylazo)-2-naphthol was studied.The results showed that the maximum absorption of Fe(Ⅱ)-TAN-OP complex was at 788 nm in pH=6.0 NaAc-HAc buffer solution.The apparent molar absorptivity of this chelate is 1.82×104 L·mol-1·cm-1.Beer′s law was obeyed in range of 0.08~0.8 μg/mL for Fe(Ⅱ).The linear equation was A=0.001 9+0.304 9 x,R=0.999 7.The method was applied to the determination of Fe(Ⅱ) in food with satisfactory results.

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In the presence of nonionic surfactant OP,the color reaction of Fe(Ⅱ) with 1-(2-Thiazolylazo)-2-naphthol was studied.The results showed that the maximum absorption of Fe(Ⅱ)-TAN-OP complex was at 788 nm in pH=6.0 NaAc-HAc buffer solution.The apparent molar absorptivity of this chelate is 1.82×104 L·mol-1·cm-1.Beer′s law was obeyed in range of 0.08~0.8 μg/mL for Fe(Ⅱ).The linear equation was A=0.001 9+0.304 9 x,R=0.999 7.The method was applied to the determination of Fe(Ⅱ) in food with satisfactory results.

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Available abstract

In the presence of nonionic surfactant OP,the color reaction of Fe(Ⅱ) with 1-(2-Thiazolylazo)-2-naphthol was studied.The results showed that the maximum absorption of Fe(Ⅱ)-TAN-OP complex was at 788 nm in pH=6.0 NaAc-HAc buffer solution.The apparent molar absorptivity of this chelate is 1.82×104 L·mol-1·cm-1.Beer′s law was obeyed in range of 0.08~0.8 μg/mL for Fe(Ⅱ).The linear equation was A=0.001 9+0.304 9 x,R=0.999 7.The method was applied to the determination of Fe(Ⅱ) in food with satisfactory results.

Key concepts: Molar absorptivity, Pulmonary surfactant, Chemistry, 2-Naphthol, Chelation, Absorption (acoustics), Buffer solution, Linear relationship

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