2013Hecheng huaxueRequires access

Synthesis and Optical Properties of a Novel Quinoline Derivative

Zhang Zhi-we

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Abstract

A novel quinoline derivative,8-【N-{ 4-[4-(diphenyl amine) styryl]phenyl} 】acetyl amino oxyl quinoline(1),was synthesized from triphenylamine and 8-hydroxylquinoline by formylation,Wittig-hornor reaction,substitution reaction and so on. The structure was characterized by 1H NMR,13C NMR,IR and ESI-MS. The optical properties of 1 were investigated by UV-Vis and fluorescence spectroscopies. The results showed that λmax of 1 is 300 nm and 375 nm. The maximum peak of 1 was at 450 nm under excitation wavelengths of 375 nm in EtOH.

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What this paper is about

A novel quinoline derivative,8-【N-{ 4-[4-(diphenyl amine) styryl]phenyl} 】acetyl amino oxyl quinoline(1),was synthesized from triphenylamine and 8-hydroxylquinoline by formylation,Wittig-hornor reaction,substitution reaction and so on. The structure was characterized by 1H NMR,13C NMR,IR and ESI-MS. The optical properties of 1 were investigated by UV-Vis and fluorescence spectroscopies. The results showed that λmax of 1 is 300 nm and 375 nm. The maximum peak of 1 was at 450 nm under excitation wavelengths of 375 nm in EtOH.

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Available abstract

A novel quinoline derivative,8-【N-{ 4-[4-(diphenyl amine) styryl]phenyl} 】acetyl amino oxyl quinoline(1),was synthesized from triphenylamine and 8-hydroxylquinoline by formylation,Wittig-hornor reaction,substitution reaction and so on. The structure was characterized by 1H NMR,13C NMR,IR and ESI-MS. The optical properties of 1 were investigated by UV-Vis and fluorescence spectroscopies. The results showed that λmax of 1 is 300 nm and 375 nm. The maximum peak of 1 was at 450 nm under excitation wavelengths of 375 nm in EtOH.

Key concepts: Chemistry, Formylation, Quinoline, Triphenylamine, Derivative (finance), Wittig reaction, Amine gas treating, Fluorescence

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