Rapid Determination of Total Organic Matter in Food Plastic Bag by Flow Injection Coupled with Chemiluminescence
Hanyu Shi
Abstract
Hanyu Shi
Abstract
The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154×10-10 to 1.154×10-5 mol/L (1/3Cr3+) and a detection limit of 4.476 × 10-11 mol/L (1/3Cr3+),with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity,ease of operation,rapid determination and low cost. All these figures of merits benefit its promotion and popularization.
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The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154×10-10 to 1.154×10-5 mol/L (1/3Cr3+) and a detection limit of 4.476 × 10-11 mol/L (1/3Cr3+),with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity,ease of operation,rapid determination and low cost. All these figures of merits benefit its promotion and popularization.
Key concepts: Chemiluminescence, Detection limit, Relative standard deviation, Luminol, Chemistry, Chromatography, Organic matter, Analytical Chemistry (journal)