2010Food ScienceRequires access

Rapid Determination of Total Organic Matter in Food Plastic Bag by Flow Injection Coupled with Chemiluminescence

Hanyu Shi

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Abstract

The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154×10-10 to 1.154×10-5 mol/L (1/3Cr3+) and a detection limit of 4.476 × 10-11 mol/L (1/3Cr3+),with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity,ease of operation,rapid determination and low cost. All these figures of merits benefit its promotion and popularization.

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What this paper is about

The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154×10-10 to 1.154×10-5 mol/L (1/3Cr3+) and a detection limit of 4.476 × 10-11 mol/L (1/3Cr3+),with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity,ease of operation,rapid determination and low cost. All these figures of merits benefit its promotion and popularization.

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Available abstract

The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154×10-10 to 1.154×10-5 mol/L (1/3Cr3+) and a detection limit of 4.476 × 10-11 mol/L (1/3Cr3+),with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity,ease of operation,rapid determination and low cost. All these figures of merits benefit its promotion and popularization.

Key concepts: Chemiluminescence, Detection limit, Relative standard deviation, Luminol, Chemistry, Chromatography, Organic matter, Analytical Chemistry (journal)

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