1992Acta Scicentiarum Naturalum Universitis PekinesisRequires access

The Synthesis of 2-(5-Bromo-2'-Thiazolylazo)-5-Dimethyl Amino Benzoie Acid and Its Spectro-photometric Study with the Reaction of Ni(II)

Mei Baogui

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Abstract

The 2-(5-Bromo-2'-thiazolylazo)-5-dimethyl amino benzole acid has been synthesized. The properties of the reagent and its complex formation reaction with Ni(Ⅱ) are studied. A sensitive spectrophotometric method for the determination of micro amounts of Ni(Ⅱ) has been developed. The optimum condition for determination, the linear calibration range and the interference of various foreign ions are reported. The composition, the molar absorptivity and the stability constant of MR complex are determined. The method has been applied to determination of Ni(Ⅱ) in alloy steel with satisfatory results.

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What this paper is about

The 2-(5-Bromo-2'-thiazolylazo)-5-dimethyl amino benzole acid has been synthesized. The properties of the reagent and its complex formation reaction with Ni(Ⅱ) are studied. A sensitive spectrophotometric method for the determination of micro amounts of Ni(Ⅱ) has been developed. The optimum condition for determination, the linear calibration range and the interference of various foreign ions are reported. The composition, the molar absorptivity and the stability constant of MR complex are determined. The method has been applied to determination of Ni(Ⅱ) in alloy steel with satisfatory results.

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Available abstract

The 2-(5-Bromo-2'-thiazolylazo)-5-dimethyl amino benzole acid has been synthesized. The properties of the reagent and its complex formation reaction with Ni(Ⅱ) are studied. A sensitive spectrophotometric method for the determination of micro amounts of Ni(Ⅱ) has been developed. The optimum condition for determination, the linear calibration range and the interference of various foreign ions are reported. The composition, the molar absorptivity and the stability constant of MR complex are determined. The method has been applied to determination of Ni(Ⅱ) in alloy steel with satisfatory results.

Key concepts: Molar absorptivity, Reagent, Chemistry, Analytical Chemistry (journal), Ion, Calibration, Stability constants of complexes, Spectrophotometry

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