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Catalytic kinetic spectrophotometric determination of trace palladium

Wang Xiao

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Abstract

A new catalytic kinetic spectrophotometric method for determination of trace palladium was proposed. The method was based on catalytic effect of palladium(Ⅱ) on the oxidation of acid chrome blue K by hydrogn peroxide in a medium of H 2SO 4. The linear range was found to be 5 97×10 -4 μg/mL ~2.6×10 -2 μg/mL for Pd(Ⅱ). It was applied to the determination of palladium in synthesized samples and palladium catalyst samples.

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A new catalytic kinetic spectrophotometric method for determination of trace palladium was proposed. The method was based on catalytic effect of palladium(Ⅱ) on the oxidation of acid chrome blue K by hydrogn peroxide in a medium of H 2SO 4. The linear range was found to be 5 97×10 -4 μg/mL ~2.6×10 -2 μg/mL for Pd(Ⅱ). It was applied to the determination of palladium in synthesized samples and palladium catalyst samples.

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Available abstract

A new catalytic kinetic spectrophotometric method for determination of trace palladium was proposed. The method was based on catalytic effect of palladium(Ⅱ) on the oxidation of acid chrome blue K by hydrogn peroxide in a medium of H 2SO 4. The linear range was found to be 5 97×10 -4 μg/mL ~2.6×10 -2 μg/mL for Pd(Ⅱ). It was applied to the determination of palladium in synthesized samples and palladium catalyst samples.

Key concepts: Palladium, Chemistry, Catalysis, Kinetic energy, Linear range, Inorganic chemistry, Spectrophotometry, Nuclear chemistry

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