2006•Jilin Normal University JournalRequires access

Hydrothermal Synthesis,Crystal Structure and Fluorescence of Coordination Polymer [Zn_2(imidazole)_4]·H_2O

Guofeng Li

Abstract

A coordination polymer,[Zn_2(imidazole)_4]·H_2O has been obtained by using hydrothermal synthesis and characterized by elemental analysis,IR,TG,fluorescence spectrum and X-ray single crystal diffraction.The compound crystallized in the tetragonal system,space group I4_1cd,a=2.3496(71) nm,b=2.3496(71) nm,c=1.2449(87) nm,z=16,V=6.873(6) nm~3,Dc=1.608 g/cm~3,R_1=0.0274,ωR~2=0.0562.

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Key concepts: Imidazole, Coordination polymer, Hydrothermal circulation, Tetragonal crystal system, Fluorescence, Crystallography, Coordination complex, Hydrothermal synthesis