2010Journal of Tonghua Normal UniversityRequires access

Hydrothermal Synthesis and Crystal Structure of One-dimensional Coordination Polymer [Zn(Hmal)(phen)(H_2O)]_n

Zhi‐Tao Wang

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Abstract

A one-dimensional coordination polymer,[Zn(Hmal)(phen)(H2O)]n(H3mal = malic acid,phen = 1,10-phenanthroline) has been obtained by using hydrothermal synthesis and characterized by elemental analysis,IR spectrum and single-crystal X-ray diffraction.The compound crystallized in the orthorhombic system,space group Pna2(1) with a= 9.5805(11),b= 19.927(2),c= 8.1752(9),z= 4,V = 1844.7(3)3,Dc= 1.671g/ cm3,F(000) = 796,μ = 1.611 mm-1,R1 = 0.0292,wR2 = 0.0769.

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A one-dimensional coordination polymer,[Zn(Hmal)(phen)(H2O)]n(H3mal = malic acid,phen = 1,10-phenanthroline) has been obtained by using hydrothermal synthesis and characterized by elemental analysis,IR spectrum and single-crystal X-ray diffraction.The compound crystallized in the orthorhombic system,space group Pna2(1) with a= 9.5805(11),b= 19.927(2),c= 8.1752(9),z= 4,V = 1844.7(3)3,Dc= 1.671g/ cm3,F(000) = 796,μ = 1.611 mm-1,R1 = 0.0292,wR2 = 0.0769.

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Available abstract

A one-dimensional coordination polymer,[Zn(Hmal)(phen)(H2O)]n(H3mal = malic acid,phen = 1,10-phenanthroline) has been obtained by using hydrothermal synthesis and characterized by elemental analysis,IR spectrum and single-crystal X-ray diffraction.The compound crystallized in the orthorhombic system,space group Pna2(1) with a= 9.5805(11),b= 19.927(2),c= 8.1752(9),z= 4,V = 1844.7(3)3,Dc= 1.671g/ cm3,F(000) = 796,μ = 1.611 mm-1,R1 = 0.0292,wR2 = 0.0769.

Key concepts: Orthorhombic crystal system, Coordination polymer, Hydrothermal circulation, Crystallography, Hydrothermal synthesis, Crystal structure, Polymer, Chemistry

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