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Synthesis of Butyl Lactate Catalyzed by Cation Exchange Resin Modified Cerium Sulfate

Hui Zhou

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Abstract

The cation exchange resin modified by cerium sulfate was used as catalyst for the synthesis of butyl lactate from lac-tic acid and n-butyl alcohol.The effects of catalyst amount,molar ratio of n-butyl alcohol to lactic acid,reaction time,catalyst reuse,and water-carrying agent on the yield were investigated.The catalyst had high activity,and could be separated easily and reused.The optimum reaction parameters were determined as follows: lactic acid 0.2mol,molar ratio of alcohol to acid 2.0,catalyst 2.0g and reaction time 80min.Under these conditions,the yield of butyl lactate was up to 95.2%.

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The cation exchange resin modified by cerium sulfate was used as catalyst for the synthesis of butyl lactate from lac-tic acid and n-butyl alcohol.The effects of catalyst amount,molar ratio of n-butyl alcohol to lactic acid,reaction time,catalyst reuse,and water-carrying agent on the yield were investigated.The catalyst had high activity,and could be separated easily and reused.The optimum reaction parameters were determined as follows: lactic acid 0.2mol,molar ratio of alcohol to acid 2.0,catalyst 2.0g and reaction time 80min.Under these conditions,the yield of butyl lactate was up to 95.2%.

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Available abstract

The cation exchange resin modified by cerium sulfate was used as catalyst for the synthesis of butyl lactate from lac-tic acid and n-butyl alcohol.The effects of catalyst amount,molar ratio of n-butyl alcohol to lactic acid,reaction time,catalyst reuse,and water-carrying agent on the yield were investigated.The catalyst had high activity,and could be separated easily and reused.The optimum reaction parameters were determined as follows: lactic acid 0.2mol,molar ratio of alcohol to acid 2.0,catalyst 2.0g and reaction time 80min.Under these conditions,the yield of butyl lactate was up to 95.2%.

Key concepts: Catalysis, Alcohol, Yield (engineering), Cerium, Chemistry, Lactic acid, Molar ratio, Ion-exchange resin

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