2008Applied Chemical IndustryRequires access

Synthesis of butyl paraben catalyzed by modified strong acid cation ion exchange resin by cerium sulfate

Liming Zhang

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Abstract

Strong acid cation ion exchange resin catalyst modified by cerium sulfate,P-hydroxybenzoic acid and n-butyl alcohol reacted to form butyl paraben.The factors influencing the yield were discussed,including amount of catalyst,the mole ratio of reactants,reaction time and so on.The experimental results showed that p-hydroxybenzoic acid 0.05 mol,molar ratio of alcohol to acid 3 ∶1,the catalyst 0.5 g and reaction time 5 h,the yield can reach 93.1%.It was the efficient,economic and environmental friendly catalyst.

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What this paper is about

Strong acid cation ion exchange resin catalyst modified by cerium sulfate,P-hydroxybenzoic acid and n-butyl alcohol reacted to form butyl paraben.The factors influencing the yield were discussed,including amount of catalyst,the mole ratio of reactants,reaction time and so on.The experimental results showed that p-hydroxybenzoic acid 0.05 mol,molar ratio of alcohol to acid 3 ∶1,the catalyst 0.5 g and reaction time 5 h,the yield can reach 93.1%.It was the efficient,economic and environmental friendly catalyst.

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Available abstract

Strong acid cation ion exchange resin catalyst modified by cerium sulfate,P-hydroxybenzoic acid and n-butyl alcohol reacted to form butyl paraben.The factors influencing the yield were discussed,including amount of catalyst,the mole ratio of reactants,reaction time and so on.The experimental results showed that p-hydroxybenzoic acid 0.05 mol,molar ratio of alcohol to acid 3 ∶1,the catalyst 0.5 g and reaction time 5 h,the yield can reach 93.1%.It was the efficient,economic and environmental friendly catalyst.

Key concepts: Catalysis, Chemistry, Ion-exchange resin, Yield (engineering), Alcohol, Cerium, Molar ratio, Paraben

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