2009•Thermosetting ResinRequires access

Study on curing kinetics of cyanate ester resin modified with epoxy resin

NI Li-zhong

Open publisher page 0 citations

Abstract

The curing procedure of bisphenol A cyanate ester resin modified by copolymerization with epoxy E-51 and alicyclic epoxy resin R-122 was studied by differential scanning calorimetry(DSC).According to Kissinger equation and Crane theory,the apparent activation energy and reaction order were obtained.They were 60.522 kJ/mol and 0.89 respectively.The curing reaction was nearly a first order reaction.The initial curing temperature,peak curing tempetature and temination curing temperature was 132.1 ℃,168.7 ℃,and 246.0 ℃ respectively.The results showed that the epoxy resins could promote the curing of BADCy and the copolmerization system could completely cured at 177 ℃.

About this research paper

What this paper is about

The curing procedure of bisphenol A cyanate ester resin modified by copolymerization with epoxy E-51 and alicyclic epoxy resin R-122 was studied by differential scanning calorimetry(DSC).According to Kissinger equation and Crane theory,the apparent activation energy and reaction order were obtained.They were 60.522 kJ/mol and 0.89 respectively.The curing reaction was nearly a first order reaction.The initial curing temperature,peak curing tempetature and temination curing temperature was 132.1 ℃,168.7 ℃,and 246.0 ℃ respectively.The results showed that the epoxy resins could promote the curing of BADCy and the copolmerization system could completely cured at 177 ℃.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The curing procedure of bisphenol A cyanate ester resin modified by copolymerization with epoxy E-51 and alicyclic epoxy resin R-122 was studied by differential scanning calorimetry(DSC).According to Kissinger equation and Crane theory,the apparent activation energy and reaction order were obtained.They were 60.522 kJ/mol and 0.89 respectively.The curing reaction was nearly a first order reaction.The initial curing temperature,peak curing tempetature and temination curing temperature was 132.1 ℃,168.7 ℃,and 246.0 ℃ respectively.The results showed that the epoxy resins could promote the curing of BADCy and the copolmerization system could completely cured at 177 ℃.

Key concepts: Cyanate ester, Epoxy, Curing (chemistry), Materials science, Bisphenol A, Differential scanning calorimetry, Cyanate, Activation energy

Related papers

Back to paper searchBrowse research topicsOriginal source
Study on curing kinetics of cyanate ester resin modified with epoxy resin — Research Paper | ScholarLens