2013Zhongguo youzhiRequires access

Biodiesel production by low temperature lipase catalyzed transesterification

Xuelin Zhang, Xianghua Tang, Junjun Li, Song Tuo, Mu YueLin, Xu Bo, Yang Yun-juan, Zunxi Huang

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Abstract

The production of biodiesel from rapeseed oil by lipase catalyzed transesterification with methanol at low temperature was studied.The effects of molar ratio of methanol to oil,dosage of lipase,reaction time,reaction temperature and water dosage on transesterification were studied by single factor experiment and orthogonal experiment.The results showed that the optimal conditions were as follows:reaction temperature 20 ℃,reaction time 12 h,molar ratio of methanol to oil 4∶ 1,dosage of lipase 105 U/g and water dosage 20%.Under the optimal conditions,the conversion rate of fatty acid methyl ester reached 97%.

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What this paper is about

The production of biodiesel from rapeseed oil by lipase catalyzed transesterification with methanol at low temperature was studied.The effects of molar ratio of methanol to oil,dosage of lipase,reaction time,reaction temperature and water dosage on transesterification were studied by single factor experiment and orthogonal experiment.The results showed that the optimal conditions were as follows:reaction temperature 20 ℃,reaction time 12 h,molar ratio of methanol to oil 4∶ 1,dosage of lipase 105 U/g and water dosage 20%.Under the optimal conditions,the conversion rate of fatty acid methyl ester reached 97%.

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Available abstract

The production of biodiesel from rapeseed oil by lipase catalyzed transesterification with methanol at low temperature was studied.The effects of molar ratio of methanol to oil,dosage of lipase,reaction time,reaction temperature and water dosage on transesterification were studied by single factor experiment and orthogonal experiment.The results showed that the optimal conditions were as follows:reaction temperature 20 ℃,reaction time 12 h,molar ratio of methanol to oil 4∶ 1,dosage of lipase 105 U/g and water dosage 20%.Under the optimal conditions,the conversion rate of fatty acid methyl ester reached 97%.

Key concepts: Transesterification, Biodiesel, Lipase, Methanol, Biodiesel production, Catalysis, Fatty acid methyl ester, Chemistry

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