Dispersive Liquid–Liquid Microextraction of Silver Prior to Determination by Microsample Introduction-Flame Atomic Absorption Spectrometry

A new simple and sensitive method has been proposed for rapid determination of trace levels of silver in environmental water samples, using dispersive liquid–liquid microextraction (DLLME) prior to its microsample introduction-flame atomic absorption spectrometry. Under the optimum conditions, the linear range was 0.1–7 µg L−1 and limit of detection was 0.018 µg L−1. The relative standard deviation for 0.50 and 5.00 µg L−1 of silver in water sample was 4.0 and 1.7%, respectively. The relative recoveries of silver from tap, well, river, and seawater samples at spiking levels of 1.00 and 5.00 µg L−1 were in the range of 86.4–98.6%.