2013Energy ProcediaOpen access

Evaluation of carbon dioxide absorption by amine based absorbent

Yasuhiro Kato, Shinji Murai, Daigo Muraok, Takehiko Muramatsu, Satoshi Saito

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Abstract

Toshiba has developed amine based aqueous solution (Toshiba solvent 1, TS-1) that can significantly reduce CO2 regeneration energy compared with general 30 wt% monoethanolamine (MEA) aqueous solution and reported the results of the pilot plant of 10 t- CO2/day recovery from the flue gas of a coal- fired power plant. In order to reduce the CO2 regeneration energy further, we have developed new hindered amine based absorbent, Absorbent-A. In the present work, Absorbent-A was evaluated for CO2 absorption properties by laboratory scale apparatus. Absorbent-A was found to have the high CO2 absorption capacity and the low reaction heat. Furthermore, the CO2 regeneration energy of Absorbent-A was 45% less than that of general 30 wt% MEA aqueous solution. In future, we will additionally evaluate Absorbent-A in order to test in the pilot plant.

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Toshiba has developed amine based aqueous solution (Toshiba solvent 1, TS-1) that can significantly reduce CO2 regeneration energy compared with general 30 wt% monoethanolamine (MEA) aqueous solution and reported the results of the pilot plant of 10 t- CO2/day recovery from the flue gas of a coal- fired power plant. In order to reduce the CO2 regeneration energy further, we have developed new hindered amine based absorbent, Absorbent-A. In the present work, Absorbent-A was evaluated for CO2 absorption properties by laboratory scale apparatus. Absorbent-A was found to have the high CO2 absorption capacity and the low reaction heat. Furthermore, the CO2 regeneration energy of Absorbent-A was 45% less than that of general 30 wt% MEA aqueous solution. In future, we will additionally evaluate Absorbent-A in order to test in the pilot plant.

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Available abstract

Toshiba has developed amine based aqueous solution (Toshiba solvent 1, TS-1) that can significantly reduce CO2 regeneration energy compared with general 30 wt% monoethanolamine (MEA) aqueous solution and reported the results of the pilot plant of 10 t- CO2/day recovery from the flue gas of a coal- fired power plant. In order to reduce the CO2 regeneration energy further, we have developed new hindered amine based absorbent, Absorbent-A. In the present work, Absorbent-A was evaluated for CO2 absorption properties by laboratory scale apparatus. Absorbent-A was found to have the high CO2 absorption capacity and the low reaction heat. Furthermore, the CO2 regeneration energy of Absorbent-A was 45% less than that of general 30 wt% MEA aqueous solution. In future, we will additionally evaluate Absorbent-A in order to test in the pilot plant.

Key concepts: Amine gas treating, Flue gas, Aqueous solution, Absorption (acoustics), Solvent, Carbon dioxide, Pilot plant, Chemistry

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