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1960•Russian Chemical ReviewsOpen access

REFRACTOMETRY AS A METHOD FOR THE PHYSICOCHEMICAL ANALYSIS OF ORGANIC SYSTEMS

B. V. Ioffe

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Abstract

CONTENTS I. Introduction?53 II. Origins of the refractometric method of physicochemical analysis and its development in the first half of the 20th century?53 III. The additivity of refractive indices?56 IV. Relationship between the deviations from additivity of refractive indices, densities, and specific refractions?58 V. Unique points on refractive-index diagrams?60 VI. Classification of refractive-index isotherms?62 VII. The use of refractometry for the study of interaction between components in binary liquid systems?63

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CONTENTS I. Introduction?53 II. Origins of the refractometric method of physicochemical analysis and its development in the first half of the 20th century?53 III. The additivity of refractive indices?56 IV. Relationship between the deviations from additivity of refractive indices, densities, and specific refractions?58 V. Unique points on refractive-index diagrams?60 VI. Classification of refractive-index isotherms?62 VII. The use of refractometry for the study of interaction between components in binary liquid systems?63

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Available abstract

CONTENTS I. Introduction?53 II. Origins of the refractometric method of physicochemical analysis and its development in the first half of the 20th century?53 III. The additivity of refractive indices?56 IV. Relationship between the deviations from additivity of refractive indices, densities, and specific refractions?58 V. Unique points on refractive-index diagrams?60 VI. Classification of refractive-index isotherms?62 VII. The use of refractometry for the study of interaction between components in binary liquid systems?63

Key concepts: Refractometry, Chemistry, Refractive index, Additive function, Binary number, Refraction, Thermodynamics, Analytical Chemistry (journal)

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