1994The Journal of Chemical PhysicsRequires access

Determination of the temperature and concentration dependence of the refractive index of a liquid mixture

W. B. Li, P. N. Segrè, Robert W. Gammon, J. V. Sengers, Magne Lamvik

Open publisher page 75 citations

Abstract

We have developed a sensitive interferometric technique for measuring the temperature derivative of the refractive index of liquids with an accuracy of 0.5% as illustrated by measurements with mixtures of liquid n-hexane and toluene. In addition the concentration dependence of the refractive index of these mixtures has been measured with refractometry. The experimentally observed temperature dependence of the refractive index appears to be consistent with a modification of the Lorentz–Lorenz relation proposed by Looyenga.

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What this paper is about

We have developed a sensitive interferometric technique for measuring the temperature derivative of the refractive index of liquids with an accuracy of 0.5% as illustrated by measurements with mixtures of liquid n-hexane and toluene. In addition the concentration dependence of the refractive index of these mixtures has been measured with refractometry. The experimentally observed temperature dependence of the refractive index appears to be consistent with a modification of the Lorentz–Lorenz relation proposed by Looyenga.

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OpenAlex reports 75 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

We have developed a sensitive interferometric technique for measuring the temperature derivative of the refractive index of liquids with an accuracy of 0.5% as illustrated by measurements with mixtures of liquid n-hexane and toluene. In addition the concentration dependence of the refractive index of these mixtures has been measured with refractometry. The experimentally observed temperature dependence of the refractive index appears to be consistent with a modification of the Lorentz–Lorenz relation proposed by Looyenga.

Key concepts: Refractometry, Refractive index, Toluene, Chemistry, Derivative (finance), Refraction, Hexane, Analytical Chemistry (journal)

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