2004•中国化学快报：英文版Requires access

Analysis of the Aconitine Alkaloids in Chuanwu by Electrospray Ionization ／ Tandem Mass Spectrometry

AiMinSUN, Huili Huili, ZhiMingHUANG, Paul P. H. But, XueQinDING

Abstract

An electrospray ionization / tandem mass spectrometric (ESUMS/MS) method was developed for the simultaneous identification and analysis of three aconitine alkaloids [mesacontine (MA), hypaconitine (HA), and aconitine (A)] as intact molecules at low nanogram level in Chinese traditional medicine Chuanwu decoction as well as in human whole blood extract without chromatographic separation.

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Key concepts: Aconitine, Chemistry, Tandem mass spectrometry, Electrospray ionization, Chromatography, Mass spectrometry, Decoction, Electrospray