2011•Acta Crystallographica Section E Structure Reports OnlineOpen access

Tris(tetrahydrofuran-κO)tris[tris(thiophen-2-yl)methanolato-κO]terbium(III) tetrahydrofuran monosolvate

Michael Veith, C. Belot, Volker Hüch

Abstract

In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa-hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.

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Key concepts: Tetrahydrofuran, Tris, Terbium, Chemistry, Lanthanide, Medicinal chemistry, Crystallography, Stereochemistry