2022•Dalton TransactionsRequires access

A Zr-added Dawson-type poly(polyoxometalate)

Hai‐Lou Li, Chen Lian, Guo‐Yu Yang

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Abstract

An unprecedented Zr-added poly(POM), [H 2 N(CH 3 ) 2 ] 10 H 14 [(Zr 2 P 2 W 16 O 61 ) 3 ]·7H 2 O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.

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An unprecedented Zr-added poly(POM), [H 2 N(CH 3 ) 2 ] 10 H 14 [(Zr 2 P 2 W 16 O 61 ) 3 ]·7H 2 O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.

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Available abstract

An unprecedented Zr-added poly(POM), [H 2 N(CH 3 ) 2 ] 10 H 14 [(Zr 2 P 2 W 16 O 61 ) 3 ]·7H 2 O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.

Key concepts: Polyoxometalate, Trimer, Sulfur, Hydrothermal circulation, Catalysis, Chemistry, Crystallography, Ion

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