Cover Feature: Supramolecular Ensembles Formed via Calix[5]arene‐Fullerene Host‐Guest Interactions (Chem. Asian J. 16/2022)
T. Hirao, Takeharu Haino
Abstract
T. Hirao, Takeharu Haino
Abstract
Calix[5]arenes have drawn attention due to their encapsulation capability for fullerenes. The high binding affinity between calix[5]arene and fullerene has enabled the development of various kinds of supramolecular fullerene polymers (such as linear fullerene polymers, helical fullerene polymers, and two-dimensionally extended fullerene networks) and the structural regulation of covalent polymers. Herein, supramolecular ensembles formed via calix[5]arene-fullerene complexation are reviewed in detail. More information can be found in the Review by Takehiro Hirao and Takeharu Haino.
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Calix[5]arenes have drawn attention due to their encapsulation capability for fullerenes. The high binding affinity between calix[5]arene and fullerene has enabled the development of various kinds of supramolecular fullerene polymers (such as linear fullerene polymers, helical fullerene polymers, and two-dimensionally extended fullerene networks) and the structural regulation of covalent polymers. Herein, supramolecular ensembles formed via calix[5]arene-fullerene complexation are reviewed in detail. More information can be found in the Review by Takehiro Hirao and Takeharu Haino.
Key concepts: Fullerene, Supramolecular chemistry, Supramolecular polymers, Polymer, Calixarene, Covalent bond, Materials science, Host–guest chemistry