1977Phosphorous and Sulfur and the Related ElementsRequires access

Sulfurization of γ-oxo esters; study of the resulting sulfur compounds

Jacques Brunet, D. Paquer, PHILIPPE RIOULT

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Abstract

Treatment of aliphatic γ-oxo esters with hydrogen chloride/hydrogen sulfide gives three sulfur compounds: an alkyl-5-mercaptothiolan-2-one, an alkyl-4-thiolen-2-one and an alkyl-3-thiolen-2-one. Chemical properties of these products are reported. With aromatic γ-oxo esters we obtain a thiophenic compound.

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Treatment of aliphatic γ-oxo esters with hydrogen chloride/hydrogen sulfide gives three sulfur compounds: an alkyl-5-mercaptothiolan-2-one, an alkyl-4-thiolen-2-one and an alkyl-3-thiolen-2-one. Chemical properties of these products are reported. With aromatic γ-oxo esters we obtain a thiophenic compound.

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Available abstract

Treatment of aliphatic γ-oxo esters with hydrogen chloride/hydrogen sulfide gives three sulfur compounds: an alkyl-5-mercaptothiolan-2-one, an alkyl-4-thiolen-2-one and an alkyl-3-thiolen-2-one. Chemical properties of these products are reported. With aromatic γ-oxo esters we obtain a thiophenic compound.

Key concepts: Alkyl, Sulfur, Chemistry, Hydrogen sulfide, Organic chemistry, Hydrogen chloride, Sulfide, Hydrogen

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