Volumetric Properties of Binary Mixtures of 1,2-Dichloroethane with Ethers from 278.15–333.15 K and at Atmospheric Pressure

Using a vibrating tube density meter, the densities and speeds of sound of 1,2-dichloroethane, methyl tert -butyl ether, diisopropyl ether, and diethyl ether were measured at T = 278.15 to 333.15 K and at atmospheric pressure. The densities of the three binary mixtures (1,2-dichloroethane + ethers) were also experimentally determined. The Redlich–Kister data treatment and partial molar volume were applied to the excess molar volume of the mixtures. To conclude, the Prigogine–Flory–Patterson model was used to predict the excess molar volume of the three binary systems and to determine the most significant contribution to the excess molar volume.