pH-Sensitive Hydrogels Based on Copolymers of Chitosan with Acrylamide and Sodium Acrylate
Lidia Kropotova, Alexandra O. Grigoreva, А. Е. Мочалова
Abstract
Lidia Kropotova, Alexandra O. Grigoreva, А. Е. Мочалова
Abstract
pH-sensitive hydrogels based on chitosan-graft-poly(acrylamide-co-sodium acrylate) were synthesized via radical polymerization in solution. Ammonium persulfate was used as initiator, and various amounts of hexamine were used as a cross-linking agent. The structure of obtained hydrogels was characterized by Fourier transform infrared spectroscopy. Moisture-absorbing power of hydrogels in buffer solution with various pH value (pH = 1.65; 4.01; 12.43) was investigated. It is turned out that such a copolymers have a high moisture retention capacity (swelling index attains the value 1100%) and are capable for reusing, that makes it possible to apply the hydrogels in different areas.
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pH-sensitive hydrogels based on chitosan-graft-poly(acrylamide-co-sodium acrylate) were synthesized via radical polymerization in solution. Ammonium persulfate was used as initiator, and various amounts of hexamine were used as a cross-linking agent. The structure of obtained hydrogels was characterized by Fourier transform infrared spectroscopy. Moisture-absorbing power of hydrogels in buffer solution with various pH value (pH = 1.65; 4.01; 12.43) was investigated. It is turned out that such a copolymers have a high moisture retention capacity (swelling index attains the value 1100%) and are capable for reusing, that makes it possible to apply the hydrogels in different areas.
Key concepts: Self-healing hydrogels, Ammonium persulfate, Acrylamide, Copolymer, Chitosan, Materials science, Acrylate, Fourier transform infrared spectroscopy