2021•RSC AdvancesOpen access

Ru III (edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

Debabrata Chatterjee, Marta Chrzanowska, Anna Katafias, Maria Oszajca, Rudi van Eldik

Abstract

(edta) complexes is proposed. The role of the coordinated water molecule (by its absence or presence in the primary coordination sphere) in controlling the mechanistic pathways, outer-sphere or inner-sphere, is discussed.

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Available abstract

Key concepts: Inner sphere electron transfer, Chemistry, Hydrogen peroxide, Outer sphere electron transfer, Coordination sphere, Aqueous solution, Pyrazine, Redox