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2021•Chemical CommunicationsRequires access

Surface morphology-induced spin-crossover-inactive high-spin state in a coordination framework

Shun Sakaida, Kazuya Otsubo, Ken‐ichi Otake, Shogo Kawaguchi, Mitsuhiko Maesato, Susumu Kitagawa, Hiroshi Kitagawa

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Abstract

Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin (HS) or SCO-inactive high-spin (HS2) states. To date, the latter has only been confirmed in the bulk counterpart at gigapascal pressure.

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What this paper is about

Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin (HS) or SCO-inactive high-spin (HS2) states. To date, the latter has only been confirmed in the bulk counterpart at gigapascal pressure.

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OpenAlex reports 8 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin (HS) or SCO-inactive high-spin (HS2) states. To date, the latter has only been confirmed in the bulk counterpart at gigapascal pressure.

Key concepts: Spin crossover, Spin states, Spin (aerodynamics), Morphology (biology), Materials science, Condensed matter physics, Microstructure, Chemical physics

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