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2008•Angewandte Chemie International EditionRequires access

A Spin‐Crossover Cluster of Iron(II) Exhibiting a Mixed‐Spin Structure and Synergy between Spin Transition and Magnetic Interaction

Dayu Wu, Osamu Sato, Yasuaki Einaga, Chunying Duan

Open publisher page 184 citations

Abstract

How low can you go? An Fe(II) (4) square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

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What this paper is about

How low can you go? An Fe(II) (4) square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

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OpenAlex reports 184 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

How low can you go? An Fe(II) (4) square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

Key concepts: Spin crossover, Condensed matter physics, Spin (aerodynamics), Spin transition, Cluster (spacecraft), Square (algebra), Spin states, Crossover

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A Spin‐Crossover Cluster of Iron(II) Exhibiting a Mixed‐Spin Structure and Synergy between Spin Transition and Magnetic Interaction — Research Paper | ScholarLens