Flower-like boehmite nanopowders obtained at low temperature from Bayer liquor
Marija Milanović, Zoran Obrenović, Ivan Stijepović, Ljubica Nikolić
Abstract
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Marija Milanović, Zoran Obrenović, Ivan Stijepović, Ljubica Nikolić
Abstract
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Boehmite nanocrystalline powders were obtained by neutralization of Bayer liquor at 70?C with addition of glucose. Temperature of the neutralization induced formation of the flower-like morphology of the nanopowders. XRD and FTIR results confirmed that the single phase boehmite is formed without any other impurities. Calcination at 500?C led to the formation of transition -alumina with the retention of the flower-like morphology. Both as-synthesised and calcined powders possessed high specific surface area with mesopores between 3-6 nm in diameter. Relatively low temperature of neutralization as well as the use of low cost and ecologically friendly glucose as a surfactant are very promising for the possible application in the industrial production of alumina nanopowders.
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Boehmite nanocrystalline powders were obtained by neutralization of Bayer liquor at 70?C with addition of glucose. Temperature of the neutralization induced formation of the flower-like morphology of the nanopowders. XRD and FTIR results confirmed that the single phase boehmite is formed without any other impurities. Calcination at 500?C led to the formation of transition -alumina with the retention of the flower-like morphology. Both as-synthesised and calcined powders possessed high specific surface area with mesopores between 3-6 nm in diameter. Relatively low temperature of neutralization as well as the use of low cost and ecologically friendly glucose as a surfactant are very promising for the possible application in the industrial production of alumina nanopowders.
Key concepts: Boehmite, Calcination, Materials science, Chemical engineering, Nanocrystalline material, Neutralization, Impurity, Mesoporous material