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ChemInform Abstract: Dehydration‐Triggered Asymmetric Hydrogenation of 3‐(α‐Hydroxyalkyl)indoles.

Duo‐Sheng Wang, Jie Tang, Yong‐Gui Zhou, Mu‐Wang Chen, Chang‐Bin Yu, Ying Duan, Guo‐Fang Jiang

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Abstract

Abstract Highly enantioselective dehydration—hydrogenation of title α‐hydroxyalkylindoles is smoothly achieved under Pd‐catalysis in the presence of Bronsted acid promotor to give the corresponding 3‐alkylindolines (II) and (IV) in high to excellent yields and enantioselectivities (up to 97% e.e.).

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What this paper is about

Abstract Highly enantioselective dehydration—hydrogenation of title α‐hydroxyalkylindoles is smoothly achieved under Pd‐catalysis in the presence of Bronsted acid promotor to give the corresponding 3‐alkylindolines (II) and (IV) in high to excellent yields and enantioselectivities (up to 97% e.e.).

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Available abstract

Abstract Highly enantioselective dehydration—hydrogenation of title α‐hydroxyalkylindoles is smoothly achieved under Pd‐catalysis in the presence of Bronsted acid promotor to give the corresponding 3‐alkylindolines (II) and (IV) in high to excellent yields and enantioselectivities (up to 97% e.e.).

Key concepts: Chemistry, Dehydration, Enantioselective synthesis, Brønsted–Lowry acid–base theory, Catalysis, Organic chemistry, Combinatorial chemistry, Biochemistry

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ChemInform Abstract: Dehydration‐Triggered Asymmetric Hydrogenation of 3‐(α‐Hydroxyalkyl)indoles. — Research Paper | ScholarLens