2010•SynthesisRequires access

Alternative Synthetic Strategies for Enantioselective Construction of Halogenated Chiral Carbon Centers

Kazutaka Shibatomi

Abstract

This review focuses on the enantioselective synthesis of halogenated molecules having a chiral halocarbon center. In particular, this review discusses enantioselective transformations with haloalkenes and enantioselective α-substitutions of α-halo carbonyl compounds. Enantioselective halogen-transfer reactions are excluded from this review.

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Key concepts: Enantioselective synthesis, Chemistry, Halogen, Organic chemistry, Combinatorial chemistry, Stereochemistry, Catalysis, Alkyl