2006Journal of Chemical ResearchRequires access

Cu–Mg (24: 76) Alloy: An Efficient Catalyst for Friedel–Crafts Acylation of Arenes

Krishnappa Manjula, V. P. Jayäshankara, M. A. Päsha

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Abstract

Friedel–Crafts acylation of different arenes was carried out in the presence of Cu–Mg (24:76) alloy under microwave irradiation and solvent-free conditions. Different substrates undergo acylation predominantly at the para-position. An efficient, simple, selective Friedel–Crafts acylation reaction affords good yields of the products and the catalyst could be easily recovered and recycled.

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What this paper is about

Friedel–Crafts acylation of different arenes was carried out in the presence of Cu–Mg (24:76) alloy under microwave irradiation and solvent-free conditions. Different substrates undergo acylation predominantly at the para-position. An efficient, simple, selective Friedel–Crafts acylation reaction affords good yields of the products and the catalyst could be easily recovered and recycled.

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Available abstract

Friedel–Crafts acylation of different arenes was carried out in the presence of Cu–Mg (24:76) alloy under microwave irradiation and solvent-free conditions. Different substrates undergo acylation predominantly at the para-position. An efficient, simple, selective Friedel–Crafts acylation reaction affords good yields of the products and the catalyst could be easily recovered and recycled.

Key concepts: Friedel–Crafts reaction, Acylation, Catalysis, Microwave irradiation, Chemistry, Solvent, Organic chemistry, Alloy

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