2018Separation Science and TechnologyRequires access

Three-dimensional g-C3N4/MgO composites as a high-performance adsorbent for removal of Pb(II) from aqueous solution

Jianjun Zhou, Xionghui Ji, Xiaohui Zhou, Jing Guo, Junyu Sun, Yaochi Liu

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Abstract

A novel, three-dimensional material of g-C3N4/MgO was prepared by pyrolysis method. The adsorption behavior for Pb(II) onto g-C3N4/MgO was systematically investigated. The adsorption experiments confirmed that the g-C3N4/MgO exhibited remarkable adsorption performance owing to its rough morphology and abundant active sites on the surface. The maximum adsorption capacities for Pb(II) reached to 220.3, 226.2 and 235.1 mg/g at 308 K, 318 K and 328 K, respectively. The optimum adsorbent dosage was 1.0 g/L. The adsorption kinetics and isotherm could be well described by the pseudo-second-order model and Langmuir isotherm model, respectively. The adsorption process was spontaneous and endothermic.

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What this paper is about

A novel, three-dimensional material of g-C3N4/MgO was prepared by pyrolysis method. The adsorption behavior for Pb(II) onto g-C3N4/MgO was systematically investigated. The adsorption experiments confirmed that the g-C3N4/MgO exhibited remarkable adsorption performance owing to its rough morphology and abundant active sites on the surface. The maximum adsorption capacities for Pb(II) reached to 220.3, 226.2 and 235.1 mg/g at 308 K, 318 K and 328 K, respectively. The optimum adsorbent dosage was 1.0 g/L. The adsorption kinetics and isotherm could be well described by the pseudo-second-order model and Langmuir isotherm model, respectively. The adsorption process was spontaneous and endothermic.

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Available abstract

A novel, three-dimensional material of g-C3N4/MgO was prepared by pyrolysis method. The adsorption behavior for Pb(II) onto g-C3N4/MgO was systematically investigated. The adsorption experiments confirmed that the g-C3N4/MgO exhibited remarkable adsorption performance owing to its rough morphology and abundant active sites on the surface. The maximum adsorption capacities for Pb(II) reached to 220.3, 226.2 and 235.1 mg/g at 308 K, 318 K and 328 K, respectively. The optimum adsorbent dosage was 1.0 g/L. The adsorption kinetics and isotherm could be well described by the pseudo-second-order model and Langmuir isotherm model, respectively. The adsorption process was spontaneous and endothermic.

Key concepts: Adsorption, Endothermic process, Chemistry, Aqueous solution, Langmuir adsorption model, Kinetics, Sorption isotherm, Pyrolysis

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