Kinetics of different stages of Chinese white poplar black liquor pyrolysis
Qiang Zhao
Abstract
Qiang Zhao
Abstract
The kinetics of pyrolysis of black liquor was studied via thermogravimetric analysis of 10℃/min,20℃/min,40℃/min,50℃/min with Zsoko method.The results show that the process of kinetics consists of 4 stages,three of which have obvious weight loss peaks and the third stage has a weight-loss platform.Because the kinetics of pyrolysis is complicated,each temperature stage was taken as independent object to describe the pyrolysis behavior with different mechnism functions.In the stage of 150~450℃ pyrolysis of organic phase,the activation energy goes down with the increase of heating rates and the water content.
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The kinetics of pyrolysis of black liquor was studied via thermogravimetric analysis of 10℃/min,20℃/min,40℃/min,50℃/min with Zsoko method.The results show that the process of kinetics consists of 4 stages,three of which have obvious weight loss peaks and the third stage has a weight-loss platform.Because the kinetics of pyrolysis is complicated,each temperature stage was taken as independent object to describe the pyrolysis behavior with different mechnism functions.In the stage of 150~450℃ pyrolysis of organic phase,the activation energy goes down with the increase of heating rates and the water content.
Key concepts: Pyrolysis, Kinetics, Thermogravimetric analysis, Chemistry, Activation energy, Black liquor, Chemical engineering, Process (computing)