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2018•Dalton TransactionsRequires access

Deprotonation of a formato ligand by a cis -coordinated carbyne ligand within a bis(phenolate) tungsten complex

Tobias Schindler, Albert Paparo, Haruka Nishiyama, Thomas P. Spaniol, Hayato Tsurugi, Kazushi Mashima, Jun Okuda

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Abstract

Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(vi) complex [(OSSO)W([triple bond, length as m-dash]CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2'-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.

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What this paper is about

Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(vi) complex [(OSSO)W([triple bond, length as m-dash]CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2'-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.

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OpenAlex reports 7 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(vi) complex [(OSSO)W([triple bond, length as m-dash]CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2'-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.

Key concepts: Carbyne, Deprotonation, Ligand (biochemistry), Chemistry, Ethylene, Tungsten, Carbene, Stereochemistry

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