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ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 69. Reactions of (MoW(CC6H4Me‐4)(CO)7(η‐C5H5)) with But‐2‐yne; Crystal Structures of (MoW(μ‐C(C6H4Me‐4)C(Me)C(Me))(CO)3(η‐MeC2Me)2(η‐C5H5)) and (MoW(μ‐C(C6H4Me‐4)C(=CH2)C(H)MeC(O))(CO)6(η‐C5H5))·0.5 CH2Cl2.

Esther Delgado, M. Esther Garcı́a, John C. Jeffery, Paul Sherwood, F. Gordon A. Stone

Abstract

Abstract Treatment of the title carbyne complex (I) with an excess of butyne (II) in refluxing THF affords the title complex (III), however, at room temp. the complex (IV) is formed.

About this research paper

What this paper is about

Abstract Treatment of the title carbyne complex (I) with an excess of butyne (II) in refluxing THF affords the title complex (III), however, at room temp. the complex (IV) is formed.

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Available abstract

Abstract Treatment of the title carbyne complex (I) with an excess of butyne (II) in refluxing THF affords the title complex (III), however, at room temp. the complex (IV) is formed.

Key concepts: Carbyne, Chemistry, Carbene, Crystal structure, Metal, Crystallography, Stereochemistry, Bridging (networking)

About this research paper

What this paper is about

Why it matters

Key contribution

Method / approach

Main findings

Limitations

Applications

Available abstract

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